Issue 22, 1999

Enantioselective allylic substitution catalyzed by an iridium complex: remarkable effects of the counter cation

Abstract

Allylic substitution of a methyl carbonate of cinnamyl alcohol with the anion of dimethyl malonate gave the branched olefin with high enantioselectivity in the presence of (S)-1,1′-binaphthyl-2,2′-diyl phenyl phosphite when a combination of lithium and zinc was used as counter cation.

Article information

Article type
Paper

Chem. Commun., 1999, 2289-2290

Enantioselective allylic substitution catalyzed by an iridium complex: remarkable effects of the counter cation

K. Fuji, N. Kinoshita, T. Kawabata and K. Tanaka, Chem. Commun., 1999, 2289 DOI: 10.1039/A907680H

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