A novel homochiral magnesium bisamide base system has been prepared and reacted with a series of prochiral ketones in the presence of TMSCl to give efficient formation of the corresponding enol ethers in enantiomeric ratios of up to 95∶5.
Enantioselective deprotonation reactions using a novel homochiral magnesium amide base
K. W. Henderson, W. J. Kerr and J. H. Moir, Chem. Commun., 2000, 479 DOI: 10.1039/B000425L
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