Issue 20, 2000

Remarkable cumulative stereoselectivity in cyclopropanation with supramolecular Cu(i) catalytic complexes

Abstract

Supramolecular Cu(I) catalyst 1 exhibited 77% cumulative (dia- and enantio-) stereoselectivity and one of the highest diastereoselectivities (86% de) obtained to date in the cyclopropanation of styrene with ethyl diazoacetate.

Article information

Article type
Communication
Submitted
24 Jul 2000
Accepted
30 Aug 2000
First published
27 Sep 2000

Chem. Commun., 2000, 1993-1994

Remarkable cumulative stereoselectivity in cyclopropanation with supramolecular Cu(I) catalytic complexes

T. Portada, M. Roje, Z. Raza, V. <img border="0" src="https://www.rsc.org/images/entities/char_0043_0306.gif" alt="[C with combining breve]" xmlns="http://www.rsc.org/schema/rscart38" />aplar, M. <img border="0" src="https://www.rsc.org/images/entities/char_005a_0306.gif" alt="[Z with combining breve]" xmlns="http://www.rsc.org/schema/rscart38" />inić and V. <img border="0" src="https://www.rsc.org/images/entities/char_0053_0306.gif" alt="[S with combining breve]" xmlns="http://www.rsc.org/schema/rscart38" />unjić, Chem. Commun., 2000, 1993 DOI: 10.1039/B006057G

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