Issue 20, 2000
From the journal:

Chemical Communications

Differential electronic effects and the selective protonation of mutually transligands

Valerie Autissier,a   Richard A. Henderson*a  and  Christopher J. Pickettb  

* Corresponding authors

a Department of Chemistry, Bedson Building, University of Newcastle, Newcastle-upon-Tyne, UK
E-mail: r.a.henderson@ncl.ac.uk

b Department of Biological Chemistry, John Innes Centre, Norwich Research Park, Norwich, UK

Abstract

The rate of protonation of the nitrile carbon in trans-[Mo(N2)(NCC6H4R-4)(Ph 2PCH2CH2PPh2)2] (R = MeO, Me, H, Cl, MeCO or NO2) shows an unusual non-linear dependence on the identity of R, revealing how both kinetic and thermodynamic factors control the site of protonation in complexes containing a variety of protonatable ligands.

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Article information

DOI
https://doi.org/10.1039/B006302I
Article type
Communication
Submitted
02 Aug 2000
Accepted
05 Sep 2000
First published
27 Sep 2000

Chem. Commun., 2000, 1999-2000

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Differential electronic effects and the selective protonation of mutually trans ligands

V. Autissier, R. A. Henderson and C. J. Pickett, Chem. Commun., 2000, 1999 DOI: 10.1039/B006302I

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