Issue 11, 2000
From the journal:

Journal of the Chemical Society, Dalton Transactions

Acid and base assisted topological reorganization of gallium sulfido clusters

Thomas J. Barbarich,a   Simon G. Bott*b  and  Andrew R. Barron*a  

* Corresponding authors

a Department of Chemistry, Rice University, Houston, Texas, USA

b Department of Chemistry, University of Houston, Houston, Texas, USA

Abstract

The reaction of [(tBu)Ga(μ3-S)]4 with nPrNH2 in toluene solution yields [(tBu)6Ga6(μ3-S)4(μ-S)2(NH2nPr)2] (1), whose thermolysis in the solid state (110 °C), results in the stoichiometric conversion to [(tBu)Ga(μ3-S)]6 (ΔH ‡ = 136 kJ mol−1); in contrast, the reaction of [(tBu)Ga(μ3-S)]4 with triflic acid at room temperature yields [(tBu)Ga(μ3-S)]7.

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Article information

DOI
https://doi.org/10.1039/A908740K
Article type
Communication
Submitted
02 Nov 1999
Accepted
11 Apr 2000
First published
05 May 2000

J. Chem. Soc., Dalton Trans., 2000, 1679-1680

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Acid and base assisted topological reorganization of gallium sulfido clusters

T. J. Barbarich, S. G. Bott and A. R. Barron, J. Chem. Soc., Dalton Trans., 2000, 1679 DOI: 10.1039/A908740K

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