Issue 1, 2001
From the journal:

Chemical Communications

A persistent C–H⋯C(π) T-stacked cationElectronic supplementary information (ESI) available: DFT calculations. See http://www.rsc.org/suppdata/cc/b0/b005450j/

Colin D. Abernethy,a   Charles L. B. Macdonald,a   Jason A. C. Clyburneb  and  Alan H. Cowley*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, The University of Texas at Austin, Austin, Texas 78712, USA.
E-mail: cowley@mail.utexas.edu

b Department of Chemistry, Acadia University, Wolfville, Nova Scotia, Canada

Abstract

The reaction of 2 equivalents of 1,3-dimesitylimidazolium chloride with Cp3Yb affords the salt [bis(1,3-dimesitylimidazolium)cyclopentadienide] [bis(cyclopentadienyl)dichloroytterbate]; the T-stacked cation is composed of two imidazolium fragments that are C–H⋯C(π) hydrogen bonded to the bridging cyclopentadienide anion.

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Article information

DOI
https://doi.org/10.1039/B005450J
Article type
Communication
Submitted
30 Jun 2000
Accepted
31 Oct 2000
First published
15 Dec 2000

Chem. Commun., 2001, 61-62

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A persistent C–H⋯C(π) T-stacked cation

C. D. Abernethy, C. L. B. Macdonald, J. A. C. Clyburne and A. H. Cowley, Chem. Commun., 2001, 61 DOI: 10.1039/B005450J

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