Issue 7, 2001
From the journal:

Chemical Communications

Polarity and hydrogen-bonding of ambient to near-critical water: Kamlet–Taft solvent parameters

Jie Lu,a   James S. Brown,a   Charles L. Liottaa  and  Charles A. Eckert*a  

* Corresponding authors

a Schools of Chemical Engineering, Chemistry and Biochemistry, and Specialty Separations Center, Georgia Institute of Technology, Atlanta, GA, USA.
E-mail: cae@che.gatech.edu

Abstract

The Kamlet–Taft solvent parameters π*, α, and β of saturated liquid water have been determined from 25 to 275 °C based on solvatochromic measurements and indicate that the polarity and hydrogen-bonding of water are highly tunable properties with temperature.

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Article information

DOI
https://doi.org/10.1039/B100425P
Article type
Communication
Submitted
09 Jan 2001
Accepted
20 Feb 2001
First published
16 Mar 2001

Chem. Commun., 2001, 665-666

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Polarity and hydrogen-bonding of ambient to near-critical water: Kamlet–Taft solvent parameters

J. Lu, J. S. Brown, C. L. Liotta and C. A. Eckert, Chem. Commun., 2001, 665 DOI: 10.1039/B100425P

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