Issue 7, 2001

Neutral and cationic yttrium alkyl complexes with linked 1,4,7-triazacyclononane-amide monoanionic ancillary ligands: synthesis and catalytic ethene polymerisationElectronic supplementary information (ESI) available: experimental, spectroscopic and polymerization details. See http://www.rsc.org/suppdata/cc/b1/b101012n/Netherlands Institute for Catalysis Research (NIOK) publication no. RUG 01-4-01.

Abstract

Yttrium dialkyl complexes [N,N′-R2-tacn-N″-(CH 2)2NBut]Y(CH2SiMe3) 2 (R = Me, Pri; tacn = 1,4,7-triazacyclononane) were prepared; when activated with [PhNMe2H][B(C6F5)4] these complexes form cationic alkyl species that are active ethene polymerisation catalysts.

Supplementary files

Article information

Article type
Communication
Submitted
30 Jan 2001
Accepted
20 Feb 2001
First published
14 Mar 2001

Chem. Commun., 2001, 637-638

Neutral and cationic yttrium alkyl complexes with linked 1,4,7-triazacyclononane-amide monoanionic ancillary ligands: synthesis and catalytic ethene polymerisation

S. Bambirra, D. van Leusen, A. Meetsma, B. Hessen and J. H. Teuben, Chem. Commun., 2001, 637 DOI: 10.1039/B101012N

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