Issue 17, 2001

Highly diastereoselective dihydride formation by activation of methanol with IrCl{(S)-binap}(PPh3)

Abstract

Reaction of [IrCl{(S)-binap}(PPh3)] {(S)-3} with methanol gave one of the diastereomers of the cis,mer-dihydride, cis,mer-OC-6-44-A-[IrCl(H2){(S)-binap}(PPh3)] {(S)-4a} stereoselectively, the structure of which was determined crystallographically, whereas the reaction of (S)-3 with H2 produced a 1∶1 mixture of the diastereomers of the cis,mer-dihydride, (S)-4a and cis,mer-OC-6-44-C-[IrCl(H2){(S)-binap}(PPh3)] {(S)-4b}.

Graphical abstract: Highly diastereoselective dihydride formation by activation of methanol with IrCl{()-binap}(PPh)

Supplementary files

Article information

Article type
Communication
Submitted
13 Mar 2001
Accepted
13 Jul 2001
First published
03 Aug 2001

Chem. Commun., 2001, 1630-1631

Highly diastereoselective dihydride formation by activation of methanol with IrCl{(S)-binap}(PPh3)

K. Tani, K. Nakajima, A. Iseki and T. Yamagata, Chem. Commun., 2001, 1630 DOI: 10.1039/B102395K

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