Issue 13, 2001

Carbene transposition involving double dehydrogenation of an sp3 carbonElectronic supplementary information (ESI) available: synthetic and spectroscopic data. Crystallographic data and selected bond lengths and angle for B. See http://www.rsc.org/suppdata/cc/b1/b102422c/

Abstract

Two benzylic hydrogens of 2,6-Me2C6H3O coordinated to RuCl(PCy3)2(CHPh)+ are transferred to the benzylidene ligand, liberating toluene to form a new carbene which is covalently linked to the aryloxide ligand.

Supplementary files

Article information

Article type
Communication
Submitted
14 Mar 2001
Accepted
03 May 2001
First published
07 Jun 2001

Chem. Commun., 2001, 1158-1159

Carbene transposition involving double dehydrogenation of an sp3 carbon

J. N. Coalter III, J. C. Huffman and K. G. Caulton, Chem. Commun., 2001, 1158 DOI: 10.1039/B102422C

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