Issue 15, 2001

Different positions of the formally isolobal moieties H+ and (AuPPh3)+ in N-(5-methoxyquinolyl-8)-2,4,6-trinitroaniline and its auration product

Abstract

It has been shown by an X-ray crystallographic analysis of N-(triphenylphosphinegold)-N-(5-methoxyquinolyl-8)- 2,4,6-trinitroaniline 1 and quantum chemical calculations on N-(5-methoxyquinolyl-8)-2,4,6-trinitroaniline 2 that H+ and (AuPPh3)+ sub-units in 1 and 2 occupy different positions at the amine and quinoline nitrogen atoms, respectively.

Supplementary files

Article information

Article type
Communication
Submitted
02 Apr 2001
Accepted
20 Jun 2001
First published
11 Jul 2001

Chem. Commun., 2001, 1394-1395

Different positions of the formally isolobal moieties H+ and (AuPPh3)+ in N-(5-methoxyquinolyl-8)-2,4,6-trinitroaniline and its auration product

L. G. Kuz’mina, A. A. Bagatur’yants, A. V. Churakov and J. A. K. Howard, Chem. Commun., 2001, 1394 DOI: 10.1039/B102938J

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