Issue 17, 2001
From the journal:

Chemical Communications

The effect of diethylamine on Stille alkylations with tetraalkylstannanesElectronic Supplementary Information (ESI) available: Tables—Stille coupling of α-iodoenone 5 with Et4Sn and Me4Sn, and general procedure. See http://www.rsc.org/suppdata/cc/b1/b103072h/

M. Teresa Barros,a   Christopher D. Maycock,*b   Mariana I. Madureirab  and  M. Rita Venturab  

* Corresponding authors

a Faculdade de Ciências e Tecnologia da, Universidade Nova de Lisboa, Departamento de Química, Monte da Caparica, Portugal

b Instituto de Tecnologia Química e Biológica, Universidade Nova de Lisboa, Apartado 127, Oeiras, Portugal
E-mail: maycock@itqb.unl.pt
Fax: +351 21 4469789;
Tel: +351 21 4469775

Abstract

The addition of diethylamine to Stille alkylation reactions using stannanes improves yields by reducing β-hydride elimination and reduction reactions, it also serves as a substitute for other additives such as Cu(I)I.

Graphical abstract: The effect of diethylamine on Stille alkylations with tetraalkylstannanes

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Supplementary files

Article information

DOI
https://doi.org/10.1039/B103072H
Article type
Communication
Submitted
04 Apr 2001
Accepted
11 Jul 2001
First published
06 Aug 2001

Chem. Commun., 2001, 1662-1663

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The effect of diethylamine on Stille alkylations with tetraalkylstannanes

M. T. Barros, C. D. Maycock, M. I. Madureira and M. R. Ventura, Chem. Commun., 2001, 1662 DOI: 10.1039/B103072H

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