Issue 17, 2001
From the journal:

Chemical Communications

Nickel porphyrin nanotweezersElectronic supplementary information (ESI) available: spectroscopic data for 3–6. See http://www.rsc.org/suppdata/cc/b1/b104715a/

Stéphanie Gazeau,a   Jacques Pécauta  and  Jean-Claude Marchon*a  

* Corresponding authors

a Laboratoire de Chimie Inorganique et Biologique (CEA, CNRS, UJF), Département de Recherche Fondamentale sur la Matière Condensée, CEA-Grenoble, 38054, Grenoble cedex 9, France.
E-mail: jcmarchon@cea.fr

Abstract

A strapped chiroporphyrin free base with two 8-methylene chains linking two adjacent meso-substituents was synthesized as the α4 conformer; insertion of Ni(II) triggered a complete conversion to the αβαβ complex, and demetallation totally regenerated the strapped free base in the α4 conformation.

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Supplementary files

Article information

DOI
https://doi.org/10.1039/B104715A
Article type
Communication
Submitted
30 May 2001
Accepted
09 Jul 2001
First published
07 Aug 2001

Chem. Commun., 2001, 1644-1645

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Nickel porphyrin nanotweezers

S. Gazeau, J. Pécaut and J. Marchon, Chem. Commun., 2001, 1644 DOI: 10.1039/B104715A

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