Issue 18, 2001
From the journal:

Chemical Communications

The first example of catalytic N-oxidation of tertiary amines by tungstate-exchanged Mg–Al layered double hydroxide in water: a green protocolIICT Communication No: 4804.

B. M. Choudary,*a   B. Bharathi,a   Ch. Venkat Reddy,a   M. Lakshmi Kantama  and  K. V. Raghavana  

* Corresponding authors

a Indian Institute of Chemical Technology, Hyderabad-, India.
E-mail: choudary@iict.ap.nic.in

Abstract

A green process, using a recyclable tungstate-exchanged Mg–Al layered double hydroxide (LDH-WO42−) heterogenised catalyst and aqueous H2O2 oxidant in water, leads to N-oxidation of aliphatic tert-amines to amine N-oxides in quantitative yields, at a high rate at room temperature.

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Article information

DOI
https://doi.org/10.1039/B104754J
Article type
Communication
Submitted
31 May 2001
Accepted
23 Jul 2001
First published
28 Aug 2001

Chem. Commun., 2001, 1736-1737

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The first example of catalytic N-oxidation of tertiary amines by tungstate-exchanged Mg–Al layered double hydroxide in water: a green protocol

B. M. Choudary, B. Bharathi, Ch. V. Reddy, M. L. Kantam and K. V. Raghavan, Chem. Commun., 2001, 1736 DOI: 10.1039/B104754J

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