Issue 22, 2001
From the journal:

Chemical Communications

Ruthenium-catalysed asymmetric hydrosilylation of ketoximes using chiral oxazolinylferrocenylphosphines

Izuru Takei,a   Yoshiaki Nishibayashi,b   Youichi Ishii,c   Yasushi Mizobe,a   Sakae Uemura*b  and  Masanobu Hidai*d  

* Corresponding authors

a Institute of Industrial Science, The University of Tokyo, Komaba, Meguro-ku, Tokyo 153-8505, Japan

b Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan

c Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656, Japan

d Department of Materials Science and Technology, Faculty of Industrial Science and Technology, Science University of Tokyo, Noda, Chiba, Japan

Abstract

Chiral ruthenium(II) complexes, RuCl2(PPh3)(oxazolinylferrocenylphosphine), have been found to be effective catalysts for asymmetric hydrosilylation of ketoximes to give the corresponding primary amines in good yields with high enantioselectivities (up to 89% ee) after acid hydrolysis.

Graphical abstract: Ruthenium-catalysed asymmetric hydrosilylation of ketoximes using chiral oxazolinylferrocenylphosphines

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Article information

DOI
https://doi.org/10.1039/B106435P
Article type
Communication
Submitted
19 Jul 2001
Accepted
10 Oct 2001
First published
26 Oct 2001

Chem. Commun., 2001, 2360-2361

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Ruthenium-catalysed asymmetric hydrosilylation of ketoximes using chiral oxazolinylferrocenylphosphines

I. Takei, Y. Nishibayashi, Y. Ishii, Y. Mizobe, S. Uemura and M. Hidai, Chem. Commun., 2001, 2360 DOI: 10.1039/B106435P

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