A new structural motif for rigid C2-symmetrical propeller-shaped 1,2-diamines employing double aromatic π-stacking

James McNulty; Rouwei Mo; Alfredo Capretta; Christopher S. Frampton

doi:10.1039/B106641B

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A new structural motif for rigid C₂-symmetrical propeller-shaped 1,2-diamines employing double aromatic π-stackingElectronic supplementary data (ESI) available: colour figure showing π-stacking in compound 12. See http://www.rsc.org/suppdata/cc/b1/b106641b/

James McNulty,*^a Rouwei Mo,^a Alfredo Capretta^a and Christopher S. Frampton^b

Author affiliations

* Corresponding authors

^a Institute of Molecular Catalysis, Department of Chemistry, Brock University, St. Catharines, Ontario, Canada
E-mail: jmcnulty@chemiris.labs.brocku.ca

^b Roche Products Ltd., 40 Broadwater Rd., Welwyn Garden City, Herts, UK

Abstract

Utilization of double aromatic π-stacking interactions on a 2,3-diaminobutane framework provides a new motif for structurally rigid C₂-symmetrical propeller-shaped chiral 1,2-diamines.

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Supplementary files

Colour figure showing π-stacking of compound 12 PDB (13K)

Article information

DOI: https://doi.org/10.1039/B106641B
Article type: Communication
Submitted: 23 Jul 2001
Accepted: 12 Sep 2001
First published: 23 Oct 2001

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Chem. Commun., 2001, 2384-2385

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A new structural motif for rigid C₂-symmetrical propeller-shaped 1,2-diamines employing double aromatic π-stacking

J. McNulty, R. Mo, A. Capretta and C. S. Frampton, Chem. Commun., 2001, 2384 DOI: 10.1039/B106641B

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