Issue 21, 2001
From the journal:

Chemical Communications

Catalytic C–F activation of polyfluorinated pyridines by nickel-mediated cross-coupling reactions

Thomas Braun,*a   Robin N. Perutz*b  and  Marianna I. Sladeka  

* Corresponding authors

a Fakultät für Chemie, Universität Bielefeld, Postfach 100131, 33501 Bielefeld, Germany.
E-mail: thomas.braun@uni-bielefeld.de

b Department of Chemistry, University of York, York, UK
E-mail: rnp1@york.ac.uk

Abstract

The cross-coupling reaction of pentafluoropyridine with tributyl(vinyl)tin affording 2-vinyltetrafluoropyridine by activation of a carbon–fluorine bond is catalysed by [NiF(2-C5NF4)(PEt3)2]; a similar reaction is observed with 2,3,5,6-tetrafluoropyridine.

Graphical abstract: Catalytic C–F activation of polyfluorinated pyridines by nickel-mediated cross-coupling reactions

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Article information

DOI
https://doi.org/10.1039/B106646C
Article type
Communication
Submitted
24 Jul 2001
Accepted
20 Sep 2001
First published
09 Oct 2001

Chem. Commun., 2001, 2254-2255

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Catalytic C–F activation of polyfluorinated pyridines by nickel-mediated cross-coupling reactions

T. Braun, R. N. Perutz and M. I. Sladek, Chem. Commun., 2001, 2254 DOI: 10.1039/B106646C

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