Issue 22, 2001
From the journal:

Chemical Communications

The tetramethylpiperidinyl-1-oxide anion (TMPO–) as a ligand in lanthanide chemistry: synthesis of the per(TMPO−) complex [(ONC5H6Me4)2Sm( μ-ONC5H6Me4)]2

William J. Evans,*a   Jeremy M. Perotti,a   Robert J. Doedensa  and  Joseph W. Zillera  

* Corresponding authors

a Department of Chemistry, University of California, Irvine, CA, USA.
E-mail: wevans@uci.edu

Abstract

(C5Me5)3Sm reacts with the free radical 2,2,6,6-tetramethylpiperidinyl-1-oxy (TMPO) to form (C5Me5)2 and the per nitroxide [(η1-ONC5H6Me4)2 Sm(μ-η1∶η2-ONC5H 6Me4)]2

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Article information

DOI
https://doi.org/10.1039/B106869P
Article type
Communication
Submitted
28 Jul 2001
Accepted
14 Sep 2001
First published
25 Oct 2001

Chem. Commun., 2001, 2326-2327

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The tetramethylpiperidinyl-1-oxide anion (TMPO–) as a ligand in lanthanide chemistry: synthesis of the per(TMPO−) complex [(ONC5H6Me4)2Sm( μ-ONC5H6Me4)]2

W. J. Evans, J. M. Perotti, R. J. Doedens and J. W. Ziller, Chem. Commun., 2001, 2326 DOI: 10.1039/B106869P

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