Issue 22, 2001
From the journal:

Chemical Communications

Two alternative products from the intercalation of alkali metals into cation-defective Ruddlesden–Popper oxysulfides

Sophie G. Denisa  and  Simon J. Clarke*a  

* Corresponding authors

a Inorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford, UK
E-mail: simon.clarke@chem.ox.ac.uk

Abstract

Sodium may be topotactically inserted into the perovskite layers (under thermodynamic control) or the rock-salt layers (under kinetic control) of the cation-deficient n = 2 Ruddlesden–Popper oxysulfides Ln2Ti2O5S2 with concomitant reduction of TiIV.

Graphical abstract: Two alternative products from the intercalation of alkali metals into cation-defective Ruddlesden–Popper oxysulfides

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Article information

DOI
https://doi.org/10.1039/B107659K
Article type
Communication
Submitted
23 Aug 2001
Accepted
09 Oct 2001
First published
26 Oct 2001

Chem. Commun., 2001, 2356-2357

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Two alternative products from the intercalation of alkali metals into cation-defective Ruddlesden–Popper oxysulfides

S. G. Denis and S. J. Clarke, Chem. Commun., 2001, 2356 DOI: 10.1039/B107659K

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