Issue 24, 2001
From the journal:

Chemical Communications

New insight into the dynamic behaviour of manganese ketene complexes: evidence for the scrambling of a carbene moiety over carbonyl ligandsElectronic supplementary information (ESI) available: details of syntheses and spectral characterisation of the new complexes. See http://www.rsc.org/suppdata/cc/b1/b109218a

Yannick Ortin,a   Yannick Coppel,a   Noël Lugan,*a   René Mathieua  and  Michael J. McGlinchey‡a  

* Corresponding authors

a Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, 31077, Toulouse Cedex 4, France.
E-mail: lugan@lcc-toulouse.fr

Abstract

The carbonyl of the ketene ligand in manganese complexes of the type RCp(CO)2Mn[η2-R′(Ph)C[double bond, length as m-dash]C[double bond, length as m-dash]O] exchanges rapidly (NMR time-scale) with the CO ligands though a process that involves scrambling of a carbene moiety over the three carbonyl environments.

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Article information

DOI
https://doi.org/10.1039/B109218A
Article type
Communication
Submitted
16 Oct 2001
Accepted
07 Nov 2001
First published
30 Nov 2001

Chem. Commun., 2001, 2636-2637

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New insight into the dynamic behaviour of manganese ketene complexes: evidence for the scrambling of a carbene moiety over carbonyl ligands

Y. Ortin, Y. Coppel, N. Lugan, R. Mathieu and M. J. McGlinchey, Chem. Commun., 2001, 2636 DOI: 10.1039/B109218A

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