Evaluation of the relative importance of Ti–Cl⋯H–N hydrogen bonds and supramolecular interactions between perfluorophenyl rings in the crystal structures of [Ti(NR)Cl2(NHMe2)2] (R = iPr, C6H5 or C6F5)

Nico Adams; Andrew R. Cowley; Stuart R. Dubberley; Andrew J. Sealey; Michael E. G. Skinner; Philip Mountford

doi:10.1039/B109251K

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Evaluation of the relative importance of Ti–Cl⋯H–N hydrogen bonds and supramolecular interactions between perfluorophenyl rings in the crystal structures of [Ti(NR)Cl₂(NHMe₂)₂] (R = ⁱPr, C₆H₅ or C₆F₅)†

Nico Adams,^a Andrew R. Cowley,^a Stuart R. Dubberley,^a Andrew J. Sealey,^a Michael E. G. Skinner^a and Philip Mountford*^a

Author affiliations

* Corresponding authors

^a Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, UK
E-mail: philip.mountford@chemistry.oxford.ac.uk

Abstract

The three closely-related compounds [Ti(NⁱPr)Cl₂(NHMe₂)₂] 1, [Ti(NC₆H₅)Cl₂(NHMe₂)₂] 2 and [Ti(NC₆F₅)Cl₂(NHMe₂)₂] 3 all crystallize in the space group C2/c with the titanium atoms lying on two-fold axes at (0, y, 1/4); in compounds 1 and 2 the molecules are linked in one-dimensional infinite chains by intermolecular Ti–Cl⋯H–N hydrogen bonds along the direction of the crystallographic c axis, whereas in 3 offset face-to-face interactions between the C₆F₅ rings break down the hydrogen bonded chains.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/B109251K
Article type: Communication
Submitted: 10 Oct 2001
Accepted: 14 Nov 2001
First published: 06 Dec 2001

Download Citation

Chem. Commun., 2001, 2738-2739

Permissions

Request permissions

Evaluation of the relative importance of Ti–Cl⋯H–N hydrogen bonds and supramolecular interactions between perfluorophenyl rings in the crystal structures of [Ti(NR)Cl₂(NHMe₂)₂] (R = ⁱPr, C₆H₅ or C₆F₅)

N. Adams, A. R. Cowley, S. R. Dubberley, A. J. Sealey, M. E. G. Skinner and P. Mountford, Chem. Commun., 2001, 2738 DOI: 10.1039/B109251K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications