Issue 4, 2002
From the journal:

Chemical Communications

Aqueous enantioselective hydrogenation of methyl 2-acetamidoacrylate with Rh–MeDuPHOS occluded in PDMS

Adi Wolfson,a   Sofie Janssens,b   Ivo Vankelecom,b   Shimona Geresh,*c   Moshe Gottlieba  and  Moti Herskowitza  

* Corresponding authors

a Department of Chemical Engineering, Ben-Gurion University of the Negev, Beer-Sheva, Israel

b Center for Surface Chemistry and Catalysis, Faculty of Agricultural and Applied Biological Sciences, Catholic University, Leuven, Belgium

c Institute for Applied Biosciences, Ben-Gurion University of the Negev, Beer-Sheva, Israel
E-mail: geresh@bgumail.bgu.ac.il

Abstract

A new chiral heterogeneous catalytic system obtained by occlusion of the Rh–MeDuPHOS complex in a polydimethylsiloxane film was tested in the asymmetric hydrogenation of methyl 2-acetamidoacrylate in aqueous medium.

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Article information

DOI
https://doi.org/10.1039/B109234K
Article type
Communication
Submitted
10 Oct 2001
Accepted
21 Nov 2001
First published
07 Feb 2002

Chem. Commun., 2002, 388-389

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Aqueous enantioselective hydrogenation of methyl 2-acetamidoacrylate with Rh–MeDuPHOS occluded in PDMS

A. Wolfson, S. Janssens, I. Vankelecom, S. Geresh, M. Gottlieb and M. Herskowitz, Chem. Commun., 2002, 388 DOI: 10.1039/B109234K

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