Issue 4, 2002
From the journal:

Chemical Communications

Hydride encapsulation in s-block metal inverse crown chemistry

Daniel J. Gallagher,a   Kenneth W. Henderson,a   Alan R. Kennedy,a   Charles T. O’Hara,a   Robert E. Mulvey*a  and  René B. Rowlingsa  

* Corresponding authors

a Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow, UK
E-mail: r.e.mulvey@strath.ac.uk

Abstract

A new category of ‘inverse crown’ complex has been established through the synthesis of the disodium–dimagnesium diisopropylamide [Na2Mg2{N(Pri)2}4(μ-H)2·(toluene)2], the first such complex to exhibit hydride encapsulation, a non-planar octagonal ‘host’ ring or solvent stabilisation.

Graphical abstract: Hydride encapsulation in s-block metal inverse crown chemistry

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Article information

DOI
https://doi.org/10.1039/B110117J
Article type
Communication
Submitted
06 Nov 2001
Accepted
14 Jan 2002
First published
30 Jan 2002

Chem. Commun., 2002, 376-377

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Hydride encapsulation in s-block metal inverse crown chemistry

D. J. Gallagher, K. W. Henderson, A. R. Kennedy, C. T. O’Hara, R. E. Mulvey and R. B. Rowlings, Chem. Commun., 2002, 376 DOI: 10.1039/B110117J

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