Issue 16, 2002
From the journal:

Chemical Communications

Synthesis and coordination chemistry of a water-soluble verdazyl radical. structures and magnetic properties of M(H2O)2(vdCO2)2·2H2O (M = Co, Ni; vdCO2 = 1,5-dimethyl-6-oxo-verdazyl-3-carboxylate)

Tosha M. Barclay,a   Robin G. Hicks,*b   Martin T. Lemaire,b   Laurence K. Thompsonc  and  Zhiqiang Xuc  

* Corresponding authors

a Department of Chemistry, North Harris College, Houston, Texas, USA

b Department of Chemistry, University of Victoria, PO Box 3065, Victoria, BC, Canada
E-mail: rhicks@uvic.ca
Fax: +1 250 721-7147
Tel: +1 250 721-7181

c Department of Chemistry, Memorial University of Newfoundland, St. John’s, Nfld, Canada

Abstract

The synthesis of a verdazyl radical with a carboxylate substituent renders the radical highly soluble in water, thereby permitting the aqueous synthesis of Ni(II) and Co(II) verdazyl complexes which have been structurally and magnetically characterized.

Graphical abstract: Synthesis and coordination chemistry of a water-soluble verdazyl radical. structures and magnetic properties of M(H2O)2(vdCO2)2·2H2O (M = Co, Ni; vdCO2 = 1,5-dimethyl-6-oxo-verdazyl-3-carboxylate)

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B204851E
Article type
Communication
Submitted
18 May 2002
Accepted
20 Jun 2002
First published
09 Jul 2002

Chem. Commun., 2002, 1688-1689

Permissions

Request permissions

Synthesis and coordination chemistry of a water-soluble verdazyl radical. structures and magnetic properties of M(H2O)2(vdCO2)2·2H2O (M = Co, Ni; vdCO2 = 1,5-dimethyl-6-oxo-verdazyl-3-carboxylate)

T. M. Barclay, R. G. Hicks, M. T. Lemaire, L. K. Thompson and Z. Xu, Chem. Commun., 2002, 1688 DOI: 10.1039/B204851E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements