Issue 20, 2002
From the journal:

Chemical Communications

Dibenzoeilatin: a novel ligand exhibiting remarkable complementary π–π stacking interactions†

Sheba D. Bergman,a   Dvora Reshef,a   Stanislav Groysman,a   Israel Goldberga  and  Moshe Kol*a  

* Corresponding authors

a School of Chemistry, Raymond and Beverly Sackler Faculty of Exact Sciences, Tel-Aviv University, Tel-Aviv, Israel
E-mail: moshekol@post.tau.ac.il

Abstract

The complex [Ru(bpy)2(dbneil)][PF6]2 forms discrete dimers in solution held by strong π–π stacking interactions via its distorted dibenzoeilatin ligand, indicating that planarity is not an obligatory requirement for achieving strong π-stacking, as long as complementarity between the stacking moieties can be achieved.

Graphical abstract: Dibenzoeilatin: a novel ligand exhibiting remarkable complementary π–π stacking interactions

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Article information

DOI
https://doi.org/10.1039/B206058B
Article type
Communication
Submitted
26 Jun 2002
Accepted
29 Aug 2002
First published
18 Sep 2002

Chem. Commun., 2002, 2374-2375

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Dibenzoeilatin: a novel ligand exhibiting remarkable complementary π–π stacking interactions

S. D. Bergman, D. Reshef, S. Groysman, I. Goldberg and M. Kol, Chem. Commun., 2002, 2374 DOI: 10.1039/B206058B

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