Issue 10, 2002
From the journal:

Journal of the Chemical Society, Dalton Transactions

High oxidation state aqueous organometallics. Formation and structure of an oxo-centred Cp*MoV trinuclear cation by chemical reduction of Cp*2Mo2O5

Funda Demirhan,ab   Jenny Gun,c   Ovadia Lev,c   Alexandre Modestov,c   Rinaldo Poli*a  and  Philippe Richarda  

* Corresponding authors

a Laboratoire de Synthèse et d'Electrosynthèse Organométalliques, Université de Bourgogne, Faculté de Science Gabriel, 6 Boulevard Gabriel, 21000 Dijon, France
E-mail: poli@u-bourgogne.fr

b Celal Bayar University, Faculty of Sciences & Liberal Arts, Department of Chemistry, 45030, Muradiye-Manisa, Turkey

c Div. of Environmental Sciences, Fredy and Nadine Hermann School of Applied Science, The Hebrew University of Jerusalem, Jerusalem, Israel

Abstract

Reduction of Cp*2Mo2O5 by zinc/CF3CO2H in MeOH–H2O yields a salt which is composed of [Cp*3Mo3O4(O2CCF3)3]+ and [Zn2(O2CCF3)6]2− ions after crystallisation from THF–Et2O.

Graphical abstract: High oxidation state aqueous organometallics. Formation and structure of an oxo-centred Cp*MoV trinuclear cation by chemical reduction of Cp*2Mo2O5

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Article information

DOI
https://doi.org/10.1039/B203583A
Article type
Communication
Submitted
12 Apr 2002
Accepted
12 Apr 2002
First published
22 Apr 2002

J. Chem. Soc., Dalton Trans., 2002, 2109-2111

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High oxidation state aqueous organometallics. Formation and structure of an oxo-centred Cp*MoV trinuclear cation by chemical reduction of Cp*2Mo2O5

F. Demirhan, J. Gun, O. Lev, A. Modestov, R. Poli and P. Richard, J. Chem. Soc., Dalton Trans., 2002, 2109 DOI: 10.1039/B203583A

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