Issue 12, 2003
From the journal:

Chemical Communications

A self-assembling polymer-bound rotaxane under thermodynamic control

Ken D. Johnstone,a   Nick Bampos,b   Jeremy K. M. Sandersb  and  Maxwell J. Gunter*a  

* Corresponding authors

a Chemistry, School of Biological, Biomedical and Molecular Sciences, University of New England, Armidale, N.S.W. 2351, Australia
E-mail: mgunter@metz.une.edu.au
Fax: +61 2 6773 3268
Tel: +61 2 6773 2767

b University Chemical Laboratory, Lensfield Rd, Cambridge, UK

Abstract

The thermodynamically controlled self-assembly of a neutral donor–acceptor rotaxane, stoppered via porphyrin coordination and bound to polystyrene beads is described, and the dynamic equilibrium between solid and solution phases has been examined by HR MAS nmr spectroscopy.

Graphical abstract: A self-assembling polymer-bound rotaxane under thermodynamic control

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Article information

DOI
https://doi.org/10.1039/B302071A
Article type
Communication
Submitted
21 Feb 2003
Accepted
01 May 2003
First published
16 May 2003

Chem. Commun., 2003, 1396-1397

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A self-assembling polymer-bound rotaxane under thermodynamic control

K. D. Johnstone, N. Bampos, J. K. M. Sanders and M. J. Gunter, Chem. Commun., 2003, 1396 DOI: 10.1039/B302071A

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