Issue 12, 2003
From the journal:

Chemical Communications

Functionalizing the surface of II–VI clusters: redox active centres on the adamantoid complex [Cd4Cl4{μ-(SeC5H4)Fe(C5H5)}6]2−

Terry P. Lebold,a   Donald L. B. Stringle,a   Mark S. Workentina  and  John F. Corrigan*a  

* Corresponding authors

a Department of Chemistry, The University of Western Ontario, London, Canada
E-mail: corrigan@uwo.ca
Fax: 1-519-661-3022
Tel: 1-519-661-2111 ext. 86387

Abstract

Trimethylsilylselenoferrocene 1 has been prepared in good yield. The reactive silyl group on 1 is used as a driving force for the synthesis [Cl4Cd4{μ2-Se(C5H4)Fe(C5H5)}6]2− 2, a Cd4Se6 adamantoid cluster with six surface ferrocenyl groups.

Graphical abstract: Functionalizing the surface of II–VI clusters: redox active centres on the adamantoid complex [Cd4Cl4{μ-(SeC5H4)Fe(C5H5)}6]2−

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Article information

DOI
https://doi.org/10.1039/B302829A
Article type
Communication
Submitted
12 Mar 2003
Accepted
15 Apr 2003
First published
13 May 2003

Chem. Commun., 2003, 1398-1399

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Functionalizing the surface of II–VI clusters: redox active centres on the adamantoid complex [Cd4Cl4{μ-(SeC5H4)Fe(C5H5)}6]2−

T. P. Lebold, D. L. B. Stringle, M. S. Workentin and J. F. Corrigan, Chem. Commun., 2003, 1398 DOI: 10.1039/B302829A

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