Issue 12, 2003
From the journal:

Chemical Communications

Renewable camphor-derived hydroperoxide: synthesis and use in the asymmetric epoxidation of allylic alcohols†

Alessandra Lattanzi,*a   Patrizia Iannece,a   Assunta Vicinanzaa  and  Arrigo Scettria  

* Corresponding authors

a Dipartimento di Chimica, Università di Salerno, Via S. Allende I, 84081 Baronissi, Salerno, Italy
E-mail: lattanzi@unisa.it
Fax: +39 (0)89 965296

Abstract

Renewable enantiopure tertiary furyl hydroperoxide has been easily synthesized in two steps starting from low cost (+)-(1R)-camphor and it has been used in the asymmetric epoxidation and kinetic resolution of allylic alcohols (enantioselectivities up to 46%).

Graphical abstract: Renewable camphor-derived hydroperoxide: synthesis and use in the asymmetric epoxidation of allylic alcohols

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Article information

DOI
https://doi.org/10.1039/B303904H
Article type
Communication
Submitted
08 Apr 2003
Accepted
22 Apr 2003
First published
16 May 2003

Chem. Commun., 2003, 1440-1441

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Renewable camphor-derived hydroperoxide: synthesis and use in the asymmetric epoxidation of allylic alcohols

A. Lattanzi, P. Iannece, A. Vicinanza and A. Scettri, Chem. Commun., 2003, 1440 DOI: 10.1039/B303904H

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