Issue 16, 2003
From the journal:

Chemical Communications

Catalytic synthesis of thiobutyrolactones via CO insertion into the C–S bond of thietanes in the presence of a heterodinuclear organoplatinum–cobalt complex

Masaki Furuya,a   Susumu Tsutsuminai,a   Hiroto Nagasawa,a   Nobuyuki Komine,a   Masafumi Hiranoa  and  Sanshiro Komiya*a  

* Corresponding authors

a Department of Applied Chemistry, Faculty of Technology, Tokyo University of Agriculture and Technology, 2-24-16 Nakacho, Koganei, Tokyo 184-8588, Japan
E-mail: komiya@cc.tuat.ac.jp
Fax: +81-42-387-7500
Tel: +81-42-388-7043

Abstract

Heterodinuclear organoplatinum-cobalt complex having a 1,2-bis(diphenylphosphino)ethane ligand (dppe)MePt–Co(CO)4 catalyzes CO insertion into the C–S bond of thietanes in THF at 100 °C under 1.0 MPa of CO for 2 h to give γ-thiobutyrolactone in quantitative yield.

Graphical abstract: Catalytic synthesis of thiobutyrolactones via CO insertion into the C–S bond of thietanes in the presence of a heterodinuclear organoplatinum–cobalt complex

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/B305799B
Article type
Communication
Submitted
23 May 2003
Accepted
26 Jun 2003
First published
09 Jul 2003

Chem. Commun., 2003, 2046-2047

Permissions

Request permissions

Catalytic synthesis of thiobutyrolactones via CO insertion into the C–S bond of thietanes in the presence of a heterodinuclear organoplatinum–cobalt complex

M. Furuya, S. Tsutsuminai, H. Nagasawa, N. Komine, M. Hirano and S. Komiya, Chem. Commun., 2003, 2046 DOI: 10.1039/B305799B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements