Issue 21, 2003
From the journal:

Chemical Communications

Metallo-phosphorylation of alkynes: reaction of alkynes with Cp2Zr(1-butene)(PR3) and chlorophosphate†

Chunbo Lai,a   Chanjuan Xi,*a   Chao Chen,a   Mingming Maa  and  Xiaoyin Honga  

* Corresponding authors

a Key Laboratory for Bioorganic Phosphorus Chemistry of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China
E-mail: cjxi@tsinghua.edu.cn
Fax: 86-10-62618239
Tel: 86-10-62782695

Abstract

Reaction of alkynes with Cp2ZrBu2 and chlorophosphate in the presence PR3 to form zircono-alkenylphosphonates, which can be converted into various β-functionalized alkenylphosphonates.

Graphical abstract: Metallo-phosphorylation of alkynes: reaction of alkynes with Cp2Zr(1-butene)(PR3) and chlorophosphate

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Article information

DOI
https://doi.org/10.1039/B308595C
Article type
Communication
Submitted
24 Jul 2003
Accepted
27 Sep 2003
First published
07 Oct 2003

Chem. Commun., 2003, 2736-2737

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Metallo-phosphorylation of alkynes: reaction of alkynes with Cp2Zr(1-butene)(PR3) and chlorophosphate

C. Lai, C. Xi, C. Chen, M. Ma and X. Hong, Chem. Commun., 2003, 2736 DOI: 10.1039/B308595C

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