Issue 21, 2003
From the journal:

Chemical Communications

Isolation of C–H⋯C(π) complexes from the reaction of stable carbenes with hydrocarbons

Silvia Filipponi,a   Jamie N. Jones,a   Jennifer A. Johnson,a   Alan H. Cowley,*a   Fabrizia Grepionib  and  Dario Bragac  

* Corresponding authors

a Department of Chemistry and Biochemistry, The University of Texas at Austin, 1 University Station A5300, Austin, Texas 78712, USA
E-mail: cowley@mail.utexas.edu
Fax: (512) 471-6822
Tel: (512) 471-7484

b Dipartimento di Chimica, Università di Sassari, Via Vienna 2, 07100 Sassari, Italy

c Dipartimento di Chimica G. Ciamician, Università di Bologna, Via Selmi 2, 40126 Bologna, Italy

Abstract

Several imidazolium–hydrocarbon salts have been isolated from the reaction of stable carbenes with hydrocarbons and some of the products have been structurally characterized showing ion pair formation in the solid state characterized by the presence of well defined and transferable C–H⋯C(π) interactions.

Graphical abstract: Isolation of C–H⋯C(π) complexes from the reaction of stable carbenes with hydrocarbons

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Article information

DOI
https://doi.org/10.1039/B309168F
Article type
Communication
Submitted
31 Jul 2003
Accepted
04 Sep 2003
First published
02 Oct 2003

Chem. Commun., 2003, 2716-2717

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Isolation of C–H⋯C(π) complexes from the reaction of stable carbenes with hydrocarbons

S. Filipponi, J. N. Jones, J. A. Johnson, A. H. Cowley, F. Grepioni and D. Braga, Chem. Commun., 2003, 2716 DOI: 10.1039/B309168F

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