Issue 24, 2003
From the journal:

Chemical Communications

Lanthanide complexes derived from (R)-1,1′-binaphthyl-2,2′-bis(neopentylamine) – {Li(THF)4}{Ln[(R)-C20H12N2(C10H22)]2} (Ln = Sm, Yb) – novel catalysts for enantioselective intramolecular hydroamination†

Jacqueline Collin,*a   Jean-Claude Daran,b   Emmanuelle Schulza  and  Alexander Trifonov*c  

* Corresponding authors

a Laboratoire de Catalyse Moléculaire, ICMMO, Université Paris-Sud, 91405 Orsay, France

b Laboratoire de Chimie de Coordination, 205 route de Narbonne, 31077 Toulouse, France

c G. A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences, Tropinia 49, 603600 Nizhny Novgorod GSP-445, Russia
E-mail: jacollin@icmo.u-psud.fr.
Fax: 33 (0) 1 69154680
Tel: 33 (0) 1 69154740

Abstract

The complexes {Li(THF)4}{Ln[(R)-C20H12N2(C10H22)]2} (Ln = Sm, Yb) have been synthesized, fully characterized and found to be efficient and enantioselective catalysts for intramolecular hydroamination of 1-(aminomethyl)-1-allylcyclohexane.

Graphical abstract: Lanthanide complexes derived from (R)-1,1′-binaphthyl-2,2′-bis(neopentylamine) – {Li(THF)4}{Ln[(R)-C20H12N2(C10H22)]2} (Ln = Sm, Yb) – novel catalysts for enantioselective intramolecular hydroamination

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Article information

DOI
https://doi.org/10.1039/B310954B
Article type
Communication
Submitted
09 Sep 2003
Accepted
16 Oct 2003
First published
07 Nov 2003

Chem. Commun., 2003, 3048-3049

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Lanthanide complexes derived from (R)-1,1′-binaphthyl-2,2′-bis(neopentylamine) – {Li(THF)4}{Ln[(R)-C20H12N2(C10H22)]2} (Ln = Sm, Yb) – novel catalysts for enantioselective intramolecular hydroamination

J. Collin, J. Daran, E. Schulz and A. Trifonov, Chem. Commun., 2003, 3048 DOI: 10.1039/B310954B

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