Issue 11, 2004
From the journal:

Chemical Communications

Biosynthesis of phomactins: common intermediate phomactatriene and taxadiene†

Tetsuo Tokiwano,a   Eri Fukushi,b   Taeko Endoa  and  Hideaki Oikawa*a  

* Corresponding authors

a Division of Chemistry, Graduate School of Science, Hokkaido University, Sapporo 060-0810, Japan
E-mail: hoik@sci.hokudai.ac.jp

b GC-MS & NMR Laboratory, Graduate School of Agriculture, Hokkaido University, Sapporo 060-8589, Japan

Abstract

The stereochemical course of GGDP cyclization in the biosynthesis of phomactins is proposed by the stereochemistry of a cyclization product, phomacta-1(14),3,7-triene, isolated from Phomasp. and the results of incorporation experiments with [1-13C]- and [1,2-13C2]acetates.

Graphical abstract: Biosynthesis of phomactins: common intermediate phomactatriene and taxadiene

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Article information

DOI
https://doi.org/10.1039/B401377H
Article type
Communication
Submitted
30 Jan 2004
Accepted
14 Apr 2004
First published
10 May 2004

Chem. Commun., 2004, 1324-1325

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Biosynthesis of phomactins: common intermediate phomactatriene and taxadiene

T. Tokiwano, E. Fukushi, T. Endo and H. Oikawa, Chem. Commun., 2004, 1324 DOI: 10.1039/B401377H

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