Issue 11, 2004
From the journal:

Chemical Communications

Methanolysis of acyl–Pd(ii) complexes relevant to CO/ethene coupling reactions†

Jianke Liu,a   Brian T. Heaton,a   Jonathan A. Iggo*a  and  Robin Whymana  

* Corresponding authors

a Department of Chemistry, Donnan and Robert Robinson Laboratories, University of Liverpool, P. O. Box 147, Liverpool, UK
E-mail: iggo@liv.ac.uk
Fax: 44 151 794 3588
Tel: 44 151 794 3538

Abstract

Alcoholysis of acyl–Pd(II) complexes relevant to palladium catalysed CO/ethene coupling reactions such as polyketone synthesis/alkoxycarbonylation reactions is shown, in a highly active catalyst system, to proceed via coordination of methanol to the Pd centre prior to nucleophilic attack at the acyl carbon.

Graphical abstract: Methanolysis of acyl–Pd(ii) complexes relevant to CO/ethene coupling reactions

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B402275K
Article type
Communication
Submitted
10 Feb 2004
Accepted
02 Apr 2004
First published
28 Apr 2004

Chem. Commun., 2004, 1326-1327

Permissions

Request permissions

Methanolysis of acyl–Pd(II) complexes relevant to CO/ethene coupling reactions

J. Liu, B. T. Heaton, J. A. Iggo and R. Whyman, Chem. Commun., 2004, 1326 DOI: 10.1039/B402275K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements