Issue 4, 2005
From the journal:

Chemical Communications

A cyclic tetra-nuclear dinitrosyl iron complex [Fe(NO)2(imidazolate)]4: synthesis, structure and stability†

Ximeng Wang,a   Eric B. Sundberg,a   Lijuan Li,*a   Katherine A. Kantardjieff,b   Steven R. Herron,b   Mark Limc  and  Peter C. Fordc  

* Corresponding authors

a Department of Chemistry and Biochemistry, California State University, Long Beach, CA, USA
E-mail: lli@csulb.edu

b Department of Chemistry and Biochemistry and the W. M. Keck Foundation Center for Molecular Structure, California State University, Fullerton, USA

c Department of Chemistry and Biochemistry, University of California, Santa Barbara, CA, USA

Abstract

A novel cyclic tetra-nuclear dinitrosyl iron complex [Fe(NO)2(Im-H)]4 was isolated and characterized by X-ray crystallography, and in donor solvents this fragments into 17 eāˆ’ monomeric units that give EPR spectra analogous to the g = 2.03 species seen in mammalian biology.

Graphical abstract: A cyclic tetra-nuclear dinitrosyl iron complex [Fe(NO)2(imidazolate)]4: synthesis, structure and stability

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Article information

DOI
https://doi.org/10.1039/B412086H
Article type
Communication
Submitted
05 Aug 2004
Accepted
04 Nov 2004
First published
14 Dec 2004

Chem. Commun., 2005, 477-479

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A cyclic tetra-nuclear dinitrosyl iron complex [Fe(NO)2(imidazolate)]4: synthesis, structure and stability

X. Wang, E. B. Sundberg, L. Li, K. A. Kantardjieff, S. R. Herron, M. Lim and P. C. Ford, Chem. Commun., 2005, 477 DOI: 10.1039/B412086H

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