Issue 7, 2005
From the journal:

Chemical Communications

1-Butyl-3-methylimidazolium 3,5-dinitro-1,2,4-triazolate: a novel ionic liquid containing a rigid, planar energetic anion†

Alan R. Katritzky,*a   Shailendra Singh,a   Kostyantyn Kirichenko,a   John D. Holbrey,*b   Marcin Smiglak,b   W. Matthew Reichertb  and  Robin D. Rogers*b  

* Corresponding authors

a Center for Heterocyclic Compounds, University of Florida, Department of Chemistry, Gainesville, Florida 32611, USA
E-mail: katritzky@chem.ufl.edu.

b Center for Green Manufacturing and Department of Chemistry, The University of Alabama, Tuscaloosa, Alabama 35487, USA
E-mail: jholbrey@bama.ua.edu, rdrogers@bama.ua.edu.

Abstract

The novel ionic liquid, 1-butyl-3-methylimidazolium 3,5-dinitro-1,2,4-triazolate has been synthesized and exhibits an unexpectedly low melting point (35 °C) considering the size and shape of the rigid, planar anion; analogous tetraalkylammonium salts (methyl, ethyl and n-butyl) have also been prepared and the tetraethylammonium example was characterized by single crystal X-ray diffraction.

Graphical abstract: 1-Butyl-3-methylimidazolium 3,5-dinitro-1,2,4-triazolate: a novel ionic liquid containing a rigid, planar energetic anion

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Article information

DOI
https://doi.org/10.1039/B414683B
Article type
Communication
Submitted
23 Sep 2004
Accepted
22 Nov 2004
First published
05 Jan 2005

Chem. Commun., 2005, 868-870

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1-Butyl-3-methylimidazolium 3,5-dinitro-1,2,4-triazolate: a novel ionic liquid containing a rigid, planar energetic anion

A. R. Katritzky, S. Singh, K. Kirichenko, J. D. Holbrey, M. Smiglak, W. M. Reichert and R. D. Rogers, Chem. Commun., 2005, 868 DOI: 10.1039/B414683B

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