Synthesis of elliptical vanadoborates housing bimetallic centers [Zn4(B2O4H2)(V10B28O74H8)]8− and [Mn4(C2O4)(V10B28O74H8)]10−

Mingmei Wu; Teresa S-C. Law; Herman H-Y. Sung; Jiwen Cai; Ian D. Williams

doi:10.1039/B414697B

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Synthesis of elliptical vanadoborates housing bimetallic centers [Zn₄(B₂O₄H₂)(V₁₀B₂₈O₇₄H₈)]⁸⁻ and [Mn₄(C₂O₄)(V₁₀B₂₈O₇₄H₈)]¹⁰⁻†

Mingmei Wu,^ab Teresa S-C. Law,^a Herman H-Y. Sung,^a Jiwen Cai^ab and Ian D. Williams*^a

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* Corresponding authors

^a Department of Chemistry, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China
E-mail: chwill@ust.hk
Fax: +(852) 3106-3446
Tel: +(852) 2358-7384

^b School of Chemistry and Chemical Engineering, Zhongshan (Sun Yat Sen) University, Guangzhou, China

Abstract

The hydrothermal synthesis of three new vanadoborate compounds with elliptical (V₁₀B₂₈O₇₄H₈) clusters is described. The clusters contain pairs of bimetallic Zn₂ or Mn₂ units.

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Article information

DOI: https://doi.org/10.1039/B414697B
Article type: Communication
Submitted: 23 Sep 2004
Accepted: 11 Jan 2005
First published: 09 Feb 2005

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Chem. Commun., 2005, 1827-1829

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Synthesis of elliptical vanadoborates housing bimetallic centers [Zn₄(B₂O₄H₂)(V₁₀B₂₈O₇₄H₈)]⁸⁻ and [Mn₄(C₂O₄)(V₁₀B₂₈O₇₄H₈)]¹⁰⁻

M. Wu, T. S-C. Law, H. H-Y. Sung, J. Cai and I. D. Williams, Chem. Commun., 2005, 1827 DOI: 10.1039/B414697B

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Chemical Communications