Reactivity of electrophilic μ-phosphinidene complexes with heterocumulenes: formation of the first σ-π-aminophosphaimine complexes [Mn2(CO)8{μ-η1,η2-P(NiPr2)![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
NR}] and diazoalkane insertions into metal–phosphorus bonds†
Abstract
The bridging phosphinidene complexes [Mn2(CO)8(μ-PNiPr2)] and [Co2(CO)4(μ-dppm)(
μ-PNR2)]
(NR2
= NiPr2, TMP) react with heterocumulenes RN3, CH2N2 and Ph2CNN to form complexes with μ-η1,η2-aminophosphaimine, μ-η1,η2-aminophosphaalkene and μ-η1,η2-aminophosphadiphenylmethylazaimine
![Graphical abstract: Reactivity of electrophilic μ-phosphinidene complexes with heterocumulenes: formation of the first σ-π-aminophosphaimine complexes [Mn2(CO)8{μ-η1,η2-P(NiPr2) [[double bond, length as m-dash]] NR}] and diazoalkane insertions into metal–phosphorus bonds](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=B505472A&imageInfo.ImageIdentifier.Year=2005)
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![[double bond, length as m-dash]](https://www.rsc.org/images/entities/h2_char_e001.gif)
NR}] and diazoalkane insertions into metal–phosphorus bonds
