Issue 32, 2005
From the journal:

Chemical Communications

A two-dimensional clathrate hydrate sandwiched by planar arrays of a copper complex†

Riichi Miyamoto,a   Rika Tanaka Hamazawa,a   Masakazu Hirotsu,a   Takanori Nishioka,a   Isamu Kinoshita*a  and  L. James Wright*b  

* Corresponding authors

a Department of Molecular Materials Science, Osaka City University, 3-3-138 Sugimoto, Osaka 558-8585, Japan
E-mail: isamu@sci.osaka-cu.ac.jp
Fax: +81-6-6690-2753
Tel: +81-6-6605-2546

b Department of Chemistry, University of Auckland, Private Bag 92019, Auckland 1020, New Zealand
E-mail: lj.wright@auckland.ac.nz
Fax: +64-9-373-7422
Tel: +64-9-373-7599 ext 88257

Abstract

The first structurally characterised example of a 2-D clathrate hydrate spontaneously assembles when [CuF(tptm)] (1) (tptm = tris(2-pyridylthio)methyl) crystallises from toluene/water solutions to produce a material in which planar arrays of [CuF(tptm)] sandwich and hydrogen bond to continuous 2-D sheets of water that incorporate toluene molecules at regular intervals.

Graphical abstract: A two-dimensional clathrate hydrate sandwiched by planar arrays of a copper complex

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Article information

DOI
https://doi.org/10.1039/B505681K
Article type
Communication
Submitted
25 Apr 2005
Accepted
23 May 2005
First published
15 Jun 2005

Chem. Commun., 2005, 4047-4049

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A two-dimensional clathrate hydrate sandwiched by planar arrays of a copper complex

R. Miyamoto, R. T. Hamazawa, M. Hirotsu, T. Nishioka, I. Kinoshita and L. J. Wright, Chem. Commun., 2005, 4047 DOI: 10.1039/B505681K

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