Issue 32, 2005
From the journal:

Chemical Communications

Chiral azide-bridged two-dimensional Cu(ii) compounds showing a field-induced spin–flop transition†

Young Sin You,a   Jung Hee Yoon,a   Hyoung Chan Kimb  and  Chang Seop Hong*a  

* Corresponding authors

a Department of Chemistry and Center for Electro- and Photo-Responsive Molecules, Korea University, Seoul, Republic of Korea
E-mail: cshong@korea.ac.kr

b Material Science Lab., Korea Basic Science Institute, Daejeon, Republic of Korea

Abstract

Two azide-bridged chiral Cu(II) compounds, [Cu(R,R-dacy)(N3)2]n (1) (R,R-dacy = trans-(1R,2R)-diaminocyclohexane) and [Cu(S,S-dacy)(N3)2]n (2) (S,S-dacy = trans-(1S,2S)-diaminocyclohexane), with two-dimensional layer structures exhibiting end-to-end and end-on azide bridging patterns, were prepared and among them 1 was examined to show a field-induced spin–flop transition.

Graphical abstract: Chiral azide-bridged two-dimensional Cu(ii) compounds showing a field-induced spin–flop transition

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Article information

DOI
https://doi.org/10.1039/B507051A
Article type
Communication
Submitted
20 May 2005
Accepted
16 Jun 2005
First published
15 Jul 2005

Chem. Commun., 2005, 4116-4118

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Chiral azide-bridged two-dimensional Cu(II) compounds showing a field-induced spin–flop transition

Y. S. You, J. H. Yoon, H. C. Kim and C. S. Hong, Chem. Commun., 2005, 4116 DOI: 10.1039/B507051A

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