Issue 35, 2005
From the journal:

Chemical Communications

The synthesis of tris(perfluoroalkyl)phosphines†

Makeba B. Murphy-Jolly,a   Lesley C. Lewisa  and  Andrew J. M. Caffyn*a  

* Corresponding authors

a Department of Chemistry, The University of the West Indies, St. Augustine, Trinidad & Tobago
E-mail: acaffyn@fsa.uwi.tt
Fax: +1 (868) 645 3771
Tel: +1 (868) 662 2002 (ex3533)

Abstract

Tris(perfluoroalkyl)phosphines, of interest as tunable alternatives to the carbon monoxide ligand, can be synthesised by the nucleophile mediated reaction of perfluoroalkyltrimethylsilanes with triphenylphosphite; the method can be extended to diphosphines.

Graphical abstract: The synthesis of tris(perfluoroalkyl)phosphines

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Article information

DOI
https://doi.org/10.1039/B507752D
Article type
Communication
Submitted
01 Jun 2005
Accepted
05 Jul 2005
First published
08 Aug 2005

Chem. Commun., 2005, 4479-4480

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The synthesis of tris(perfluoroalkyl)phosphines

M. B. Murphy-Jolly, L. C. Lewis and A. J. M. Caffyn, Chem. Commun., 2005, 4479 DOI: 10.1039/B507752D

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