Silylstannations of α,β-unsaturated carbonyl compounds via the generation of Bu3Sn− in ionic liquids

Steven Dickson; Darrell Dean; Robert. D. Singer

doi:10.1039/B508400H

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Silylstannations of α,β-unsaturated carbonyl compoundsvia the generation of Bu₃Sn⁻ in ionic liquids

Steven Dickson,^a Darrell Dean^a and Robert. D. Singer*^a

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^a Department of Chemistry, Saint Mary's University, Halifax, Nova Scotia, Canada

Abstract

The tributylstannyl anion, Bu₃Sn⁻, can be generated in imidazolium based ionic liquids from Me₃SiSnBu₃ and reacted with α,β-unsaturated carbonyl compounds to afford 3-tributylstannylated products in good yields.

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Article information

DOI: https://doi.org/10.1039/B508400H
Article type: Communication
Submitted: 15 Jun 2005
Accepted: 13 Jul 2005
First published: 04 Aug 2005

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Chem. Commun., 2005, 4474-4476

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Silylstannations of α,β-unsaturated carbonyl compounds via the generation of Bu₃Sn⁻ in ionic liquids

S. Dickson, D. Dean and Robert. D. Singer, Chem. Commun., 2005, 4474 DOI: 10.1039/B508400H

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Chemical Communications