Issue 46, 2005
From the journal:

Chemical Communications

Unprecedented reactivity in the Morita–Baylis–Hillman reaction; intramolecular α-alkylation of enones using saturated alkyl halides†

Marie E. Krafft,*a   Kimberly A. Seibert,a   Thomas F. N. Haxella  and  Chitaru Hirosawaa  

* Corresponding authors

a Department of Chemistry and Biochemistry, Florida State University, Tallahassee, FL 32306-4390, USA
E-mail: mek@chem.fsu.edu
Fax: 850-644-7409
Tel: 850-644-2297

Abstract

sp3 Hybridized electrophiles, never before used in the organomediated Morita–Baylis–Hillman reaction, now facilitate the formation of five- and six-membered enone cycloalkylation products.

Graphical abstract: Unprecedented reactivity in the Morita–Baylis–Hillman reaction; intramolecular α-alkylation of enones using saturated alkyl halides

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Article information

DOI
https://doi.org/10.1039/B512665G
Article type
Communication
Submitted
07 Sep 2005
Accepted
10 Oct 2005
First published
04 Nov 2005

Chem. Commun., 2005, 5772-5774

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Unprecedented reactivity in the Morita–Baylis–Hillman reaction; intramolecular α-alkylation of enones using saturated alkyl halides

M. E. Krafft, K. A. Seibert, T. F. N. Haxell and C. Hirosawa, Chem. Commun., 2005, 5772 DOI: 10.1039/B512665G

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