Issue 48, 2005
From the journal:

Chemical Communications

Ruthenium trihydrides with N-heterocyclic carbeneligands: effects on quantum mechanical exchange coupling†

Aled L. Jones,a   G. Sean McGrady,*a   Peter Sirscha  and  Jonathan W. Steed*b  

* Corresponding authors

a Department of Chemistry, University of New Brunswick, Fredericton, N.B., Canada
E-mail: smcgrady@unb.ca
Fax: +1 506 453 4981
Tel: +1 506 452 6340

b Department of Chemistry, University of Durham, South Road, Durham, UK
E-mail: jon.steed@dur.ac.uk
Fax: +44 (0)191384 4737
Tel: +44 (0)191 334 2085

Abstract

Ruthenium trihydrides containing N-heterocyclic carbene ligands display large quantum mechanical exchange couplings in their 1H NMR spectra: DFT calculations are used to explore this phenomenon and to compare them to their phosphine congeners.

Graphical abstract: Ruthenium trihydrides with N-heterocyclic carbene ligands: effects on quantum mechanical exchange coupling

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Article information

DOI
https://doi.org/10.1039/B512760B
Article type
Communication
Submitted
08 Sep 2005
Accepted
17 Oct 2005
First published
04 Nov 2005

Chem. Commun., 2005, 5994-5996

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Ruthenium trihydrides with N-heterocyclic carbene ligands: effects on quantum mechanical exchange coupling

A. L. Jones, G. S. McGrady, P. Sirsch and J. W. Steed, Chem. Commun., 2005, 5994 DOI: 10.1039/B512760B

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