Functionalised 9-(1,3-dithiol-2-ylidene)thioxanthene derivatives: a C60 conjugate as an ambipolar organic field effect transistor (OFET)

Samia Amriou; Aravinda Mehta; Martin R. Bryce

doi:10.1039/B500500K

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Functionalised 9-(1,3-dithiol-2-ylidene)thioxanthene derivatives: a C₆₀ conjugate as an ambipolar organic field effect transistor (OFET)†

Samia Amriou,^a Aravinda Mehta^a and Martin R. Bryce*^a

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* Corresponding authors

^a Department of Chemistry and Centre for Molecular and Nanoscale Electronics, University of Durham, Durham, UK
E-mail: m.r.bryce@durham.ac.uk

Abstract

Thioxanthene has been converted into 9-(1,3-dithiol-2-ylidene)thioxanthene derivatives which are new two-electron π-donors; an ambipolar OFET has been fabricated from the covalent 9-(1,3-dithiol-2-ylidene)thioxanthene–C₆₀ diad system 6.

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Supplementary files

Characterisation data for 6; details of OFET device fabrication procedures; figures of the UPM3 optimised geometry of 6, the localisation of HOMO and LUMO orbitals of 6, and the cyclic voltammogram of 6 PDF (347K)

Article information

DOI: https://doi.org/10.1039/B500500K
Article type: Communication
Submitted: 11 Jan 2005
Accepted: 17 Feb 2005
First published: 28 Feb 2005

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J. Mater. Chem., 2005,15, 1232-1234

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Functionalised 9-(1,3-dithiol-2-ylidene)thioxanthene derivatives: a C₆₀ conjugate as an ambipolar organic field effect transistor (OFET)

S. Amriou, A. Mehta and M. R. Bryce, J. Mater. Chem., 2005, 15, 1232 DOI: 10.1039/B500500K

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Journal of Materials Chemistry