Issue 7, 2006
From the journal:

Chemical Communications

A paramagnetic Cu(i)/Cu(ii)/Zn(ii) coordination polymer with multiple CN-binding modes and its solid-state NMR characterization†

Liang Ouyang,a   Pedro M. Aguiar,b   Raymond J. Batchelor,a   Scott Kroeker*b  and  Daniel B. Leznoff*a  

* Corresponding authors

a Department of Chemistry, Simon Fraser University, 8888 University Drive, Burnaby, B.C., Canada
E-mail: dleznoff@sfu.ca

b Department of Chemistry, University of Manitoba, Winnipeg, Manitoba, Canada
E-mail: scott_kroeker@umanitoba.ca

Abstract

A Cu(I)/Cu(II)/Zn(II) mixed-valent [Cu(en)2][Zn(NC)4(CuCN)2] polymer, which has a 2-D layer structure with six structurally inequivalent cyanides in four distinct bonding modes, has been prepared; structurally informative 13C and 15N MAS NMR spectra of this paramagnetic system are readily observable.

Graphical abstract: A paramagnetic Cu(i)/Cu(ii)/Zn(ii) coordination polymer with multiple CN-binding modes and its solid-state NMR characterization

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Article information

DOI
https://doi.org/10.1039/B512430A
Article type
Communication
Submitted
01 Sep 2005
Accepted
28 Nov 2005
First published
05 Jan 2006

Chem. Commun., 2006, 744-746

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A paramagnetic Cu(I)/Cu(II)/Zn(II) coordination polymer with multiple CN-binding modes and its solid-state NMR characterization

L. Ouyang, P. M. Aguiar, R. J. Batchelor, S. Kroeker and D. B. Leznoff, Chem. Commun., 2006, 744 DOI: 10.1039/B512430A

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