Issue 10, 2006
From the journal:

Chemical Communications

Bimodal association of a bis-1,2,3-dithiazolyl radical

Alicea A. Leitch,a   Courtney E. McKenzie,b   Richard T. Oakley,*a   Robert W. Reed,a   John F. Richardsonb  and  Lenora D. Sawyera  

* Corresponding authors

a Department of Chemistry, University of Waterloo, Waterloo, Ontario, Canada
E-mail: oakley@uwaterloo.ca

b Department of Chemistry, University of Louisville, Louisville, Kentucky, USA

Abstract

The N-ethyl pyrazine-bridged bis-1,2,3-dithiazolyl radical 2 (R1 = Et) associates at room temperature as a C–C bonded σ-dimer which, on heating, converts to a laterally S–S σ-bonded structure.

Graphical abstract: Bimodal association of a bis-1,2,3-dithiazolyl radical

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Article information

DOI
https://doi.org/10.1039/B517098B
Article type
Communication
Submitted
05 Dec 2005
Accepted
16 Jan 2006
First published
25 Jan 2006

Chem. Commun., 2006, 1088-1090

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Bimodal association of a bis-1,2,3-dithiazolyl radical

A. A. Leitch, C. E. McKenzie, R. T. Oakley, R. W. Reed, J. F. Richardson and L. D. Sawyer, Chem. Commun., 2006, 1088 DOI: 10.1039/B517098B

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