Issue 16, 2006
From the journal:

Chemical Communications

A non-heme dinuclear iron(ii) complex containing a single, unsupported hydroxo bridge†‡

Jesús Pitarch López,a   Holger Kämpf,a   Matthias Grunert,b   Philipp Gütlich,b   Frank W. Heinemann,c   Raju Prakashc  and  Andreas Grohmann*a  

* Corresponding authors

a Technische Universität Berlin, Institut für Chemie, Sekretariat C2, Straße des 17. Juni 135, Berlin, Germany
E-mail: andreas.grohmann@chem.tu-berlin.de
Fax: +49 30 314 22935

b Johannes Gutenberg Univeristät Mainz, Institut für Anorganische Chemie und Analytische Chemie, Staudingerweg 9, Mainz, Germany

c Universität Erlangen-Nürnberg, Institut für Anorganische Chemie, Egerlandstraße 1, Erlangen, Germany

Abstract

Complexation of the tetrapodal pentadentate NN4 ligand 2,6-C5H3N[CMe(CH2NH2)2]2 (1) with iron(II) perchlorate hydrate in methanol, in the presence of N-methylimidazole, produces a diferrous complex with a single, unsupported μ-OH ligand between two {(1)FeII} coordination modules.

Graphical abstract: A non-heme dinuclear iron(ii) complex containing a single, unsupported hydroxo bridge

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Article information

DOI
https://doi.org/10.1039/B517635B
Article type
Communication
Submitted
13 Dec 2005
Accepted
20 Feb 2006
First published
09 Mar 2006

Chem. Commun., 2006, 1718-1720

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A non-heme dinuclear iron(II) complex containing a single, unsupported hydroxo bridge

J. P. López, H. Kämpf, M. Grunert, P. Gütlich, F. W. Heinemann, R. Prakash and A. Grohmann, Chem. Commun., 2006, 1718 DOI: 10.1039/B517635B

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