Characterisation of the thermally accessible spin triplet state in dimers of the 7π ClCNSSS+˙ in the solid state

T. Stanley Cameron; Andreas Decken; Radoslaw M. Kowalczyk; Eric J. L. McInnes; Jack Passmore; Jeremy M. Rawson; Konstantin V. Shuvaev; Laurence K. Thompson

doi:10.1039/B602843H

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Characterisation of the thermally accessible spin triplet state in dimers of the 7π ClCNSSS⁺˙ in the solid state†

T. Stanley Cameron,^a Andreas Decken,^b Radoslaw M. Kowalczyk,^c Eric J. L. McInnes,^c Jack Passmore,*^b Jeremy M. Rawson,^d Konstantin V. Shuvaev^b and Laurence K. Thompson^e

Author affiliations

* Corresponding authors

^a Department of Chemistry, Dalhousie University, Halifax, Nova Scotia, Canada

^b Department of Chemistry, University of New Brunswick, Fredericton, Canada
E-mail: passmore@unb.ca
Fax: 1-506-453-4981
Tel: 1-506-453-4821

^c EPSRC Multi-Frequency EPR Service, School of Chemistry, The University of Manchester, Oxford Road, Manchester, UK

^d Department of Chemistry, The University of Cambridge, Lensfield Road, Cambridge, UK

^e Department of Chemistry, Memorial University of Newfoundland, St.John's, Canada

Abstract

[ClCNSSS]₂²⁺ is the first example of a thiazyl radical dimer where population of a thermally excited spin triplet state has been detected, as is proved by VT-powder and single-crystal EPR spectroscopy.

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Article information

DOI: https://doi.org/10.1039/B602843H
Article type: Communication
Submitted: 24 Feb 2006
Accepted: 05 Apr 2006
First published: 27 Apr 2006

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Chem. Commun., 2006, 2277-2279

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Characterisation of the thermally accessible spin triplet state in dimers of the 7π ClCNSSS⁺˙ in the solid state

T. S. Cameron, A. Decken, R. M. Kowalczyk, E. J. L. McInnes, J. Passmore, J. M. Rawson, K. V. Shuvaev and L. K. Thompson, Chem. Commun., 2006, 2277 DOI: 10.1039/B602843H

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